Rubber Antioxidants

Rubber Antioxidants Manufacturer & Supplier

 

Rubber antioxidants help protect rubber compounds against degradation caused by heat, oxygen, ozone, light, and repeated flexing. The appropriate grade depends on the rubber polymer, operating environment, required aging resistance, and finished-product appearance.
Heze Great Bridge Chemical Co., Ltd. supplies a range of rubber antioxidants for tire manufacturing and industrial rubber processing. Available grades include 6PPD, IPPD, DTPD (3100), TMQ, ODPA, MB, MMB, MBZ, MMBZ, SP, BHT, and NDBC.
These products serve different formulation requirements.

 
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Product Types & Grades

 

Product / Grade

Main Selection Considerations

Typical Application Focus

6PPD

Ozone protection, flex-crack resistance, and oxidative aging protection; staining characteristics must be considered

Tire compounds and dynamic rubber products

IPPD

Ozone-related aging, flex cracking, heat aging, and light aging protection

Natural rubber, SBR, BR, and NBR compounds

DTPD (3100)

Long-term antiozonant and anti-aging protection; can be evaluated in combination with PPD antioxidants

Tires, hoses, belts, and industrial rubber products

TMQ

Heat and oxidative aging protection with relatively slow migration in rubber

Tires, tubes, belts, hoses, and general rubber products

ODPA

Protection against thermal oxidation, flex cracking, and ozone aging

NR, SBR, NBR, and CR compounds

MB / MMB / MBZ / MMBZ

Grade-specific antioxidant selection; evaluate compatibility, staining, and zinc content where applicable

Selected industrial and specialty rubber formulations

SP

Liquid antioxidant grade; selection should follow its chemical identity and product-specific TDS

Applications specified in the product technical documentation

BHT

Phenolic antioxidant for selected formulations

Rubber and related industrial applications

NDBC

Zinc-containing antioxidant grade; evaluate its suitability against the polymer and formulation requirements

Selected rubber compounds

 

Choosing Between Key Antioxidant Grades
6PPD: Commonly selected when ozone cracking and flex fatigue are major concerns, particularly in tire compounds.

IPPD: Offers ozone, flex-crack, thermal-oxidative, and light-aging protection. Its staining characteristics should be considered.

DTPD: Used as an antiozonant and antioxidant in tire and industrial rubber compounds. It can be evaluated in combination with 6PPD or IPPD where long-term protection is required.

TMQ: A common choice for heat-aging protection in a range of elastomers.

ODPA: Provides a combination of heat, oxygen, flexing, and ozone protection in suitable rubber systems.

 

Technical Specifications

 

Product

Appearance

Melting Point / Initial MP

Heating Loss / Loss on Drying

Other Published Indicators

6PPD

Dark purple pastilles

≥45.0°C

≤0.30% (60–70°C)

Assay (GC) ≥96.0%; Ash ≤0.15%

IPPD

Gray-purple to purple-brown pastilles

≥70.0°C

≤0.30%

Assay (GC) ≥95.0%; Ash ≤0.20%

TMQ

Amber to brown flakes or granules

80–100°C

≤0.30%

Ash ≤0.30%

ODPA

Light brown or off-white powder

≥87°C

≤0.50%

Residue on ignition ≤0.30%

DTPD (3100)

Brownish-gray grains

90–100°C

≤0.50% at 65°C

Ash ≤0.30% at 800°C

MB

White powder

≥290°C

≤0.30%

Ash ≤0.30%; 150 μm sieve residue ≤0.10%

MMB

Light yellow or off-white

≥250°C

≤0.40%

Ash ≤0.40%

MBZ

White powder

≥240°C

≤0.50%

Zinc content: 18.0–20.0%

BHT

White crystals or crystalline powder

69.0–70.5°C

≤0.50%

Purity: 99%; Ash: 0.01%

The values above are based on the product specifications currently published by Great Bridge Chemical. Test conditions and specification limits are grade-specific. Confirm the latest TDS and agreed purchase specification before ordering.

 
Applications
 
01/

Tire Manufacturing
6PPD, IPPD, DTPD, and TMQ are relevant grades for tire compounds. PPD-based antioxidants are commonly used to address ozone cracking and flex fatigue, while TMQ supports resistance to thermal-oxidative aging.

02/

Conveyor Belts and Transmission Belts
Antioxidants help protect belt compounds against heat, oxygen, ozone, and repeated flexing. The selection depends on belt construction, rubber formulation, and operating conditions.

03/

Rubber Hoses and Sealing Components
ODPA, TMQ, and other suitable grades can be evaluated for hose compounds, sealing rings, gaskets, and industrial rubber components exposed to heat and environmental aging.

04/

Automotive Rubber Parts
Antioxidants are used in selected formulations for engine mounts, shock absorbers, sealing strips, dust covers, and other rubber components subject to repeated deformation and environmental exposure.

05/

Wire and Cable Products
Suitable antioxidant grades can be incorporated into rubber insulation and sheathing compounds to support resistance to thermal and environmental aging. Polymer compatibility and end-use requirements should be checked before selection.

06/

Rubber Sheets, Shoes, and General Industrial Products
Selected antioxidant grades are used in rubber sheets, rubber soles, industrial seals, and other molded or extruded rubber products. Product selection should account for aging protection, appearance, and formulation compatibility.

 

Performance & Quality Control
 

Key Formulation Considerations
Ozone and Flex-Crack Resistance: Evaluate 6PPD, IPPD, and DTPD for dynamic rubber products exposed to ozone and repeated deformation.

Heat and Oxidative Aging: Consider TMQ and suitable alternative grades according to polymer type and operating temperature.

Multiple Aging Factors: ODPA can be evaluated where heat, oxygen, flexing, and ozone protection are required.

Staining and Discoloration: PPD-based antioxidants can cause staining. For light-colored or non-staining products, alternative grades should be evaluated through color and aging tests.

Dispersion and Compatibility: Check the interaction between the antioxidant, rubber polymer, fillers, and other compounding ingredients to reduce the risk of poor dispersion or blooming.

Rubber Antioxidants DTPD 3100

 

Rubber Antioxidants DTPD

Production and Quality Management
Heze Great Bridge Chemical Co., Ltd. was established in 2014 and operates under an ISO 9001:2015-certified quality management system.
Its rubber chemical production system includes reactors, dryers, pulverizers, granulators, mixing systems, automated process control, and quality testing equipment.
Depending on the product grade, relevant inspection items include:
Appearance and physical form
Melting point or initial melting point
Assay or active content
Heating loss or loss on drying
Ash or residue on ignition
Zinc content for applicable grades
Sieve residue and particle-size control
TDS, SDS, and batch COA can be requested for product evaluation and incoming quality inspection. Buyers should confirm the applicable documents and test methods for each selected grade.

 

Packaging & Supply

 

 

25 kg paper-plastic composite bags with PE inner liners.
500 kg to 1000 kg flexible intermediate bulk containers (FIBC / Jumbo bags) with moisture-barrier film.
Pastille / Granular form factor option for automated chemical weighing systems.
Palletized, shrink-wrapped, and edge-board protected loads for ocean container transport.

Port-adjacent warehouse facilities support scheduled contract releases and emergency safety-stock delivery schedules.

 

 

FAQ

 

 

Q: What is the difference between 6PPD, IPPD, and DTPD?

A: All three are PPD-based antioxidants used in rubber formulations requiring ozone and aging protection. 6PPD and IPPD are widely used for ozone and flex-crack protection. DTPD is also used as an antiozonant and can be evaluated in combination with 6PPD or IPPD for long-term protection. Their selection depends on the rubber formulation and service conditions.

Q: Which rubber antioxidant is suitable for tire manufacturing?

A: 6PPD, IPPD, DTPD, and TMQ are relevant options for tire compounds. PPD-based grades address ozone and flex-crack concerns, while TMQ is primarily used for heat and oxidative aging protection. The appropriate grade or combination depends on the tire component and compound formulation.

Q: Which antioxidant should I choose for heat-aging protection?

A: TMQ and ODPA are two grades to evaluate. TMQ is commonly used for heat and oxidative aging protection across different elastomers. ODPA provides protection against thermal oxidation and can also help with flex-crack and ozone aging in suitable rubber systems.

Q: Are rubber antioxidants suitable for both natural and synthetic rubber?

A: Some grades are suitable for several polymer systems, but compatibility varies. For example, the published IPPD information identifies NR, SBR, BR, and NBR applications, while ODPA information also includes CR. Buyers should confirm compatibility with the specific polymer and curing formulation before production.

Q: Can you provide technical documents and samples?

A: TDS, SDS, and batch COA can be requested for technical evaluation and incoming quality inspection. Samples are subject to grade availability and confirmation of the intended application.

Q: What are the MOQ, packaging, and delivery time?

A: These depend on the selected antioxidant grade, physical form, order quantity, and destination. DTPD and ODPA have published 25 kg packaging options. Contact our sales team to confirm the packaging, MOQ, and delivery schedule for your required grade.

 

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Request a Quote

Looking for an antioxidant for tire compounds, conveyor belts, hoses, automotive rubber parts, or other industrial applications?
Send us the following information to help identify suitable grades:
Required product grade, if known
Rubber polymer (NR, SBR, BR, NBR, CR, EPDM, or other)
Finished product and application
Main protection requirement (heat, oxygen, ozone, or flex cracking)
Staining or discoloration requirements
Required specification and physical form
Estimated order quantity and destination country

Great Bridge Chemical can provide product information, relevant technical documents, available samples, and a quotation based on your purchasing requirements.
Contact Great Bridge Chemical
Email: export@greatbridge-chem.com
Tel: +86-530-5399496
WhatsApp: 86 158 0675 1555
Request a Rubber Antioxidant Quotation.

With abundant experience, we are one of the most professional rubber antioxidants manufacturers and suppliers in China. We warmly welcome you to buy high quality rubber antioxidants in stock here and get pricelist from our factory. Good service and reasonable price are available.